Synthesis and characterization of fullerene transition metal complexes. Electronic and geometric structure of fullerene transition metal complexes and the relationship of their structure with the complexes chemical reactivities. Integration of high school biology, chemistry, mathematics and physics using calculator-based laboratory technology.
Representative Publications:
Tamara Félix, Jose E. Cortés Figueroa, Consecutive C60 Fullerene Dissociation from Ir(η2-C60)(CO)(Cl)(PPh3)2 and the Oxidative Addition of Benzene, Journal of Chemical Education, 2010, 87(4), 426-428.
T. Félix-Massa, J.E. Cortés-Figueroa, “Solvent/C60 exchange on Ir(CO)(PPH3)2(Cl)(h2-C60) and solven/solvent’ Exchange on Ir(CO)(PPH3)2(Cl)(solvent)”, Inorganic Chemistry Communications, 2009, 12, 347-350.
Elvin Igartúa-Nieves, Yessenia Ocasio-Delgado, and José E. Cortés-Figueroa, Ligand Exchange reactions of fac-(dihapto-[60]fullerene)(dihapto-1,2-bis-(diphenylphosphino)ethane tricarbonyl chromium(0), Journal of Coordination Chemistry, 2007, 60(4), 449 – 456.
Luis A. Rivera-Rivera, Yessenia Ocasio, Gisela Crespo, Debora Acevedo and José E. Cortés-Figueroa, [60]fullerene Displacement from Fac-(Dihapto-[60]fullerene)(Dihapto-1, 2-Bis-(1,10-Phenanthroline) Tricarbonyl Tungsten(0). Inorg. Chimi. Acta, 2004, 357 (3), 881 – 887.
F. Colón-Padilla, L. Rivera-Rivera, Y. Ocasio-Delgado and J. E. Cortés-Figueroa, Kinetics and Mechanisms of Ligand Exchange Reactions on (Dihapto-Buckminsterfullerene) Pentacarbonyl Tungsten (0)., Inorg. Reac. Mech. 2002, 4, 49-56.
Luis Rivera-Rivera, Frisia Colón-Padilla, Ana Del Toro-Novalés, José E. Cortés-Figueroa, PHOTOSYNTHESIS OF (DIHAPTO-BUCKMINSTERFULLERENE) PENTACARBONYL TUNGSTEN (O), Journal of Coordination Chemistry, 2001, 54(2), 143–151.
W. De Jesus, J. Cortes, J. López-Garriga, Formation of Compounds I and Compound II Ferryl Species in the Reactions of Hemoglobin I from Lucina pectinata with Hydrogen Peroxide, Arch. Biochem. Biophys., 2001, 390, 304‑308.
J. E. Cortés-Figueroa, M. S. León-Velázquez, J. Ramos, J. P. Jasinski, D. A. Keene, J. D. Zubkowski, and E. J. Valente, Crystal Structures of cis-tetracarbonylbis(tricyclohehylphosphine) Molybdenum (0) and Pentacarbonyl(tricyclohehylphosphine) Molybdenum (0), Acta Cryst. Secc. C 2000, C56, 1435-1437.
Formation of Compound I and Compound II Ferryl Species in the Reaction of Hemoglobin I from Lucina Pectinata with Hydrogen Peroxide. W. De Jesús, J. E. Cortés-Figueroa, F. A. Souto-Bachiller, L. Rodríguez, and J. López-Garriga, Archives of Biochemistry and Biophysics 2001, 390, 304-308.
Photosynthesis of (Dihapto-Buckminsterfullerene) Pentacarbonyl Tungsten (0). L. Rivera-Rivera, F. Colón- Padilla, A. Del Toro-Novalés and J. E. Cortés-Figueroa J. Coord. Chem. 2001, 54, 143.
Kinetics and Mechanisms of Ligand Exchange Reactions on (Dihapto-Buckminsterfullerene) Pentacarbonyl Tungsten (0). F. Colón-Padilla, L. Rivera-Rivera, Y. Ocasio-Delgado and J. E. Cortés-Figueroa, Inorg. React. Mech. 2002, 4, 49-56.
Using a Graphing Calculator to Determine a First-Order Rate Constant when the Infinity Reading is Unknown. J. E. Cortés-Figueroa and D. A. Moore J. Chem. Ed. 2002, 79, 1462-1464.
An Experiment for the Inorganic Chemistry Laboratory: The Sunlight Induced Photosynthesis of (h2-C60)M(CO)5 Complexes (M = W, Mo). J. E. Cortés-Figueroa J. Chem. Ed. 2003, 80, 799-800.